What year Eldorado do you own? We are not in a position to give you definite answers, however, 25psi indicates a defective exhaust valve.
Depending on the overall condition of the engine, it sounds like you may only need to remove the head and replace the defective valve, bearing in mind, it's best to have a full rebuild, including valves, valve guides, seals, and seats, especially if you pan on keeping the car. If the valves are in good shape they may need only be slightly ground so they will seal and seat properly in new valve seats. But, of course discuss your options with a knowledgeable mechanic. If it turns out to be a defective exhaust valve, I’m guessing that you can expect to spend in the range of about $400 for a complete head rebuild?