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i have a 2000 lincoln ls. the air was cool when the car was in park but not driving down the road. we put 1 can of freon in and it stayed at 35 psi the whole time but the air got colder. we put another can in and it still stayed at 35 but now the air is hot. can anyone tell me what happened?

my air was cold when my car was in park but hot when driving. i put freon in and it never went past 35 psi on the first can but the air got colder. we put another can of freon in and now the air is hot. what happened?